Search for: All records

Soot is known for its enormous and pervasive negative impacts on human health and the environmental, but there much about soot that is not well known, including the precursors and chemical mechanisms involved in its formation. Many studies have characterized species associated with incipient particles, i.e., the first particles produced during soot formation. These studies provide insight into inception mechanisms, the pathways leading from gas-phase precursors to condensed-phase particles. Potential inception mechanisms involve one (or a combination) of two classes of pathways: physical nucleation, in which precursors undergo a thermodynamic phase change and are bound together by electrostatic forces, and chemical clustering, in which precursors react to form covalently bound clusters. In a recent paper, Shao et al.1 concluded that soot inception occurs through physical nucleation and claimed to have provided direct evidence of such a mechanism. We demonstrate that this conclusion is inconsistent with (1) the consensus of published work, (2) the data, theory, and analysis on which this conclusion is nominally based, and (3) the second law of thermodynamics. We show that, contrary to their conclusions, their experimental and theoretical results provide evidence for a chemical-clustering soot-inception mechanism. 

We report light-driven levitation of macroscopic polymer films with nanostructured surface as candidates for long-duration near-space flight. We levitated centimeter-scale disks made of commercial 0.5-micron-thick mylar film coated with carbon nanotubes on one side. When illuminated with light intensity comparable to natural sunlight, the polymer disk heats up and interacts with incident gas molecules differently on the top and bottom sides, producing a net recoil force. We observed the levitation of 6-mm-diameter disks in a vacuum chamber at pressures between 10 and 30 Pa. Moreover, we controlled the flight of the disks using a shaped light field that optically trapped the levitating disks. Our experimentally validated theoretical model predicts that the lift forces can be many times the weight of the films, allowing payloads of up to 10 milligrams for sunlight-powered low-cost microflyers at altitudes of 50 to 100 km. 

Abstract Groundwater is a vital ecosystem of the global water cycle, hosting unique biodiversity and providing essential services to societies. Despite being the largest unfrozen freshwater resource, in a period of depletion by extraction and pollution, groundwater environments have been repeatedly overlooked in global biodiversity conservation agendas. Disregarding the importance of groundwater as an ecosystem ignores its critical role in preserving surface biomes. To foster timely global conservation of groundwater, we propose elevating the concept of keystone species into the realm of ecosystems, claiming groundwater as a keystone ecosystem that influences the integrity of many dependent ecosystems. Our global analysis shows that over half of land surface areas (52.6%) has a medium‐to‐high interaction with groundwater, reaching up to 74.9% when deserts and high mountains are excluded. We postulate that the intrinsic transboundary features of groundwater are critical for shifting perspectives towards more holistic approaches in aquatic ecology and beyond. Furthermore, we propose eight key themes to develop a science‐policy integrated groundwater conservation agenda. Given ecosystems above and below the ground intersect at many levels, considering groundwater as an essential component of planetary health is pivotal to reduce biodiversity loss and buffer against climate change. 

The Great Plains (GP) low-level jet (GPLLJ) contributes to GP warm season water resources (precipitation), wind resources, and severe weather outbreaks. Past research has shown that synoptic and local mesoscale physical mechanisms (Holton and Blackadar mechanisms) are required to explain GPLLJ variability. Although soil moisture–PBL interactions are central to local mechanistic theories, the diurnal effect of regional soil moisture anomalies on GPLLJ speed, northward penetration, and propensity for severe weather is not well known. In this study, two 31-member WRF-ARW stochastic kinetic energy backscatter scheme ensembles simulate a typical warm season GPLLJ case under CONUS-wide wet and dry soil moisture scenarios. In the GP (24°–48°N, 103°–90°W), ensemble mean differences in sensible heating and PBL height of 25–150 W m −2 and 100–700 m, respectively, at 2100 UTC (afternoon) culminate in GPLLJ 850-hPa wind speed differences of 1–4 m s −1 12 hours later (0900 UTC; early morning). Greater heat accumulation in the daytime PBL over dry soil impacts the east–west geopotential height gradient in the GP (synoptic conditions and Holton mechanism) resulting in a deeper thermal low in the northern GP, causing increases in the geostrophic wind. Enhanced daytime turbulent mixing over dry soil impacts the PBL structure (Blackadar mechanism), leading to increased ageostrophic wind. Overnight geostrophic and ageostrophic winds constructively interact, leading to a faster nocturnal GPLLJ over dry soil. Ensemble differences in CIN (~50–150 J kg −1 ) and CAPE (~500–1000 J kg −1 ) have implications for severe weather predictability.